荧光光谱法研究辛硫磷与牛血清白蛋白的相互作用

用荧光光谱法研究了在生理pH条件下杀虫剂辛硫磷与牛血清白蛋白(BSA)的相互作用. 结果表明: 辛硫磷对BSA的荧光有较强的猝灭作用, 该猝灭属于静态猝灭. 根据猝灭结果求得了不同温度下辛硫磷与牛血清白蛋白结合作用的结合位点数、结合常数及反应热力学参数, 并据此确定它们之间主要的相互作用力为疏水作用力. 用同步荧光光谱法探讨了辛硫磷对BSA构象的影响.     

灰度图像复原的一种空间适应性向前向后扩散模型

该文考虑退化灰度图像复原问题. 首先, 作者利用时滞正则化方法定义退化图像去噪过程和去模糊过程之间的权重函数, 将激波过滤器边缘增强模型与水平集运动去噪模型相结合, 建立一种新的图像磨光增强偏微分方程. 然后, 证明该偏微分方程初值问题黏性弱解的存在唯一性. 最后, 给出该模型的部分数值算例.     

Existence of multiple solutions for semilinear elliptic equations in the annulus

The existence of radial solutions of Δu ＋ λg（｜x｜）f（u） = 0 in annuli with Dirichlet（Dirichlet/Neumann） boundary conditions is investigated.It is proved that the problems have at least two positive radial solutions on any annulus if f is superlinear at 0 and sublinear at ∞.     

惰气熔融-热导法测定钕铁硼永磁材料中的氢

建立惰气熔融-热导法测定钕铁硼永磁材料中氢的分析方法。当氧-氢比例大于50:1时,CO对氢的测定结果产生一定的干扰,加入舒茨试剂可消除此干扰。采用标准坩埚,称样0.05g,熔融功率为2.85 kW,选择高纯镍篮和锡片做助熔剂,钕铁硼中氢释放完全。以普通钢铁参考物质建立氢校准曲线,线性相关系数r～2=0.9999,检出限为0.75μg/g。该法用于钕铁硼样品中氢的测定,测定结果与脉冲熔融飞行时间质谱-气体元素分析仪测定结果基本一致,测定结果的相对标准偏差为1.4%(n=5)。该方法可以准确测定钕铁硼永磁材料中的氢,能满足日常分析的要求。     

Sound transmission from stiffened double laminated composite plates

An analytical model is developed to investigate the sound transmission loss from orthogonally rib-stiffened double laminated composite plates structure under a plane sound wave excitation, in which first order shear deformation theory is presented for laminated composite plates. By using the space harmonic approach and virtual work principle, the sound transmission loss is described analytically. The validity and feasibility of the model are verified by comparing the present theoretical predictions with numerical results published previously. The influences of structure geometrical parameters on sound transmission loss are subsequently presented. Through numerical results, it can be concluded that the proposed analytical model is accurate and simple in solving the vibroacoustic behavior of an orthogonally rib-stiffened double laminated composite plates.     

Methods of rapid orbit forecasting after maneuvers for geostationary satellites

A geostationary (GEO) satellite may serve as a navigation satellite, but there is a problem that maneuvers frequently occur and the forces are difficult to model. Based on the technique of determining satellite orbits by transfer, a predicted orbit with high accuracy may be achieved by the method of statistical orbit determination in case of no maneuver force. The predicted orbit will soon be invalid after the maneuver starts, and it takes a long time to get a valid orbit after the maneuver ends. In order to improve ephemeris usability, the method of rapid orbit forecasting after maneuvers is studied. First, GEO satellite movement is analyzed in case of maneuvers based on the observation from the orbit measurement system by transfer. Then when a GEO satellite is in the free status just after maneuvers, the short arc observation is used to forecast the orbit. It is assumed that the common system bias and biases of each station are constant, which can be obtained from orbit determination with long arc observations. In this way, only 6 orbit elements would be solved by the method of statistical orbit determination, and the ephemeris with high accuracy may be soon obtained. Actual orbit forecasting with short arc observation for SINOSAT-1 satellite shows that, with the tracking network available, the precision of the predicted orbit (RMS of O-C) can reach about 5 m with 15 min arc observation, and about 3 m with 30 min arc observation. Supported by the National High Technology Research and Development Program of China (Grant No. 2006AA12Z322), the National Basic Research Program of China (Grant No. 2007CB815503), and the West Light Program of Chinese Academy of Sciences (Grant No. 2007LH01)     

Precise absolute positioning for a single-frequency user

A new strategy to realize precise absolute positioning for a single-frequency user is presented. In the presented strategy, the receiver clock and ambiguities are removed using the satelliteand epoch-differenced (SDED) algorithm. As a further development of the SDED algorithm, a regional augmentation network is used to generate the SDED atmospheric delays at the user. The weakened mathematic property due to the epoch-differenced operation is improved by adding the generated atmospheric delays and applying the robust estimation. To test the new approach, the 24-h data at 5 Continuous Operation Reference Station (CORS) stations in Shanghai is processed. The results show a more than 96% success rate, defined as the case where three directions achieve the desired positioning accuracy of 10 cm, when the observation is longer than 20 min. The 20-min static results show that the new method can reach an accuracy of 3.42, 4.76 and 9.26 cm in the North, East and Up directions, respectively. An experiment was carried out to assess the kinematic positioning. The results show that the kinematic positioning accuracy is 4.11, 5.31 and 4.05 cm in the north-south, east-west and height directions,respectively.     

Low dispersion finite volume scheme based on reconstruction with minimized dispersion and controllable dissipation

The reconstruction with minimized dispersion and controllable dissipation(MDCD) optimizes dispersion and dissipation separately and shows desirable properties of both dispersion and dissipation.A low dispersion finite volume scheme based on MDCD reconstruction is proposed which is capable of handling flow discontinuities and resolving a broad range of length scales.Although the proposed scheme is formally second order accurate,the optimized dispersion and dissipation make it very accurate and robust so that the rich flow features encountered in practical engineering applications can be handled properly.A number of test cases are computed to verify the performances of the proposed scheme.     

On the local fractional derivative

We present the necessary conditions for the existence of the Kolwankar-Gangal local fractional derivatives (KG-LFD) and introduce more general but weaker notions of LFDs by using limits of certain integral averages of the difference-quotient. By applying classical results due to Stein and Zygmund (1965) [16] we show that the KG-LFD is almost everywhere zero in any given intervals. We generalize some of our results to higher dimensional cases and use integral approximation formulas obtained to design numerical schemes for detecting fractional dimensional edges in signal processing.